MadSci Network: Agricultural Sciences
Query:

Re: how can ammonia be converted to nitrogen for use as a fertilizer

Date: Tue Mar 24 16:54:50 1998
Posted By: Eric Biddinger, Grad Student, Horticulture, Penn State University
Area of science: Agricultural Sciences
ID: 890769214.Ag
Message:

MadSci Network: Agricultural Sciences
Query:

Bill,

Nitrogen can be found in several different forms in the environment. There is a process in nature which converts nitrogen from one form to another as different organisms use it. This is called the Nitrogen Cycle. Some of the more important forms of nitrogen found in the Nitrogen Cycle include:

Nitrogen gas - N2
Ammonia - NH3
Ammonium - NH4+
Nitrate - NO3-

The first thing to consider with your question is what form of nitrogen can plants take up. Plants can take up only two forms of nitrogen - ammonium and nitrate.

Ammonium and nitrate are produced in several different ways. Ammonium is manufactured for agricultural and industrial use, made by nitrogen fixing bacteria, and is an end product of decomposition. Nitrate is converted from ammonium by bacteria by a process called nitrification. Nitrate is also formed by lightning strikes.

I should mention the difference between ammonia and ammonium is that ammonium is in solution with water. There is usually a equilibrium between the two forms that looks something like this:

NH3 + H2O <=> NH4+ + OH-

You might wonder what difference ammonium and nitrate have on plant growth. Ammonium is in a reduced form that the plant can use directly to form amino acids and other necessary molecules. This means it is readily available and causes an increase in vegetative growth. Nitrate, on the other hand must be reduced by the plant into ammonium before it can be used. Which fertilizer a farmer or grower will use depends on the crop being grown and the growing conditions.

For a more information on the nitrogen cycle, including a good diagram, try this web site.

Thanks for the question!

Eric J. Biddinger
Grad Student - Department of Horticulture
Penn State University
ejb190@psu.edu


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