| MadSci Network: Chemistry |
Greetings:
The answer to your question turned out to be quite difficult to track down.
I’ll explain how I found the awnser to your question so that in the future
you might use a similar process for finding information.
STEP 1.
First I asked the people that I work with your question, this usually
comes up with a solid clue. While most scientists I know are aware about
the special pens none of them knew how they work. Everyone agreed that the
checker pens were some form of chemical indicator; however, what chemicals
were being tested for on the bills was the question. Chemical indicators
are usually solutions that test for various chemical compounds and/or
acidic or base ions by turning various colors. Swimming pool and spa water
test kits have several different color indicators for testing pH levels
(acid or base), bromine and chlorine concentrations.
STEP 2
I then asked the manager at my bank about the pens and he demonstrated a
pen for me but he did not know how it worked! He also said that the bank
does not use them because they mess up good bills with marks and they do
not detect all bad bills! I then wrote down the name of the company on the
pen.
STEP 3
I then found the company that sold the checker pens to the bank on the web
and all that their pages indicated was that the pen uses a patented
chemical to check the paper money. I then also looked up a dozen other Web
pages for companies selling similar money checking pens and there were
several different types of colored or clear checker marking pens for sale
and while most of them claimed to work on money from many countries, others
claimed that they did not work on all currencies including Canadian money
etc. There were a few clues to the process being used on the web pages but
all said that the chemicals were patented.
STEP 4 (Final step)
I then made a patent search and that turned up several answers to your
question. Patent searches are an excellent way to find details about how
something that's patented works; however, it takes a bit of time to find
the correct titles and patent numbers. You can also make free patent
searches on the web at the US Patent Office server or the less busy IBM
patent server URL at:
http://patent.womplex.ibm.com/.
Once you find a patent in the topic area that you are interested in each
patent must also reference similar past patents and you can unravel the
whole process by checking the references. In general it is best to search
for the newest patent in a topic area and all previous patents will be
referenced in the chain of reference patents. I used these key words in my
patent search: COUNTERFEIT, CURRENCY, and PEN and came up with about a
dozen patents.
It appears that there are various types of currency checker pens; however,
they all look for residue chemicals in the paper left over from the paper
manufacturing process. Starch and iodide salts are the most common compound
that all the pens look for and some pens claim to also look for other trace
chemicals. Most, but not all, genuine currencies , use a special
manufacturing processes that does not leave trace chemicals such as starch
in the paper..
ANSWER:
Counterfeit currency checking pens use chemical color indicators to sense
trace chemicals left in the paper from the manufacturing process. Most
governments use special paper manufacturing processes that do not leave the
same trace chemical residues. Starch and iodate salts seem to be the most
common trace chemical residue tested for in commercial paper.
DETAILS:
The following is a typical pen advertisement at the following URL:
http://www.di-wave.com/lostp/lossp.htm
"With the Counterfeit Money Detector Pen
TEST MARK ANY AREA OF A BILL. WAIT ONE SECOND
A DARK BROWN OR BLACK MARK MEANS THAT THE BILL IS SUSPECT
A GOLD OR YELLOW MARK MEANS THAT IT IS GOOD.
The yellow mark fades away in a few days. A black mark remains until the
bill is destroyed. It will detect U.S. Dollars, French Francs, German
Marks, Japanese Yen, Hong Kong Dollars, Venezuelan Bolivars and Bahamian
Dollars.
The pen is approximately the size of a regular fountain pen. No need for
batteries.100% Guaranteed. standard paper manufacturing.
-----------------------------------------
The following are abstracts from a few of many patents that I found in the
money checking topic:
Patent Number 5393556
Title: Composition and method for detecting counterfeit paper currency
A chemical solution to detect counterfeit paper currency comprising
metallic iodine of 99.9% purity, and a solvent selected from the groups
consisting of alcohols, polyalcohols, ketones, esters of the alcohols or
the polyalcohols, with formic, acetic, propionic or lactic acid, ethers of
methyl, ethyl, propyl, or butyl alcohols, or of the polyalcohols, mixtures
of solvents selected from one or more of the groups, the selected solvent
being not completely soluble in water and being mixed, at a temperature of
20° C. with distilled water in a volumetric ratio ranging from 99 percent
to the volume of saturation of the selected solvent with the distilled
water, at the temperature of 20° C., the metallic iodine dissolved at a
temperature of 20° C., in the selected solvent.
-------------------------------------------------
Patent Number 973744
Title: A security paper authenticating system
ABSTRACT: A security paper authenticating system comprises, in
combination, a security paper carrying both starch and an iodate salt,
typically potassium iodate, and an authenticating composition comprising an
acidic solution of an iodide salt, typically potassium iodide, the system
being such that on applying the authenticating composition to authentic
security paper, as by a pen, brush or stamp pad, iodine is generated and a
characteristic starch-iodine coloration is produced. The authenticating
composition is preferably aqueous or part-aqueous, and is preferably made
acidic by means of a weak organic acid such as tartaric acid. The
authenticating composition preferably also contains an antioxidant such as
ascorbic acid. The invention extends to the paper and the authenticating
composition individually.
-------------------------------------
Patent Number 496349
Title: A method of detecting counterfeit paper currency
ABSTRACT: A method of detecting counterfeit paper currency includes
applying a test solution having an initial color to an area of a paper
currency to be tested. After waiting for a predetermined time period, the
color of the test area is compared with a predetermined standard to
determine if a reaction has taken place, whereby on the application of the
test solution to a counterfeit paper currency the net result will be a
color change from its initial color to a black coloration and for a genuine
paper currency there will be no immediate change in its initial color.
What I claim is:
1. A method of determining illegitimate paper currency by detecting the
starch content therein in excess of the genuine currency, comprising the
steps of:
(a) providing a paper currency to be tested;
(b) providing a test solution including iodine and having an initial color;
(c) applying said test solution to an area of said paper currency;
(d) waiting for a predetermined time period; and
(e) comparing the color of said area of said paper currency with a
predetermined standard to determine if a reaction has taken place;
(f) whereby on the application of said test solution to a counterfeit paper
currency the net result will be a color change from its initial color to a
black coloration due to the reaction with starch in the counterfeit paper
currency and for a genuine paper currency there will beno immediate change
in its initial color.
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Best regards from your Mad Scientist
Adrian Popa
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