MadSci Network: Chemistry
Query:

Re: Whether a glue is basic, acidic.etc. will it affect the glue? i.e bonding..

Date: Tue Feb 9 11:14:49 1999
Posted By: Todd Whitcombe, Faculty, Chemistry, University of Northern British Columbia
Area of science: Chemistry
ID: 915769966.Ch
Message:

Glue is a very specific form of adhesive, generated from the collagen or
"connective tissue" found in animal by-products, such as bone and hide. In
essence, you make glue by boiling up the various bits and extracting the
degraded collagen protein. (Without using animal bits, this can be done by 
denaturing - with vinegar - the proteins in milk.)

Different starting materials produce glues of different chemical
properties, such as pH. The acidity or basicity is a function of the
protein itself. Breaking the protein down gets you lots of little amino
acid fragments - not singular amino acids but small poly-peptides of
several hundred amino acid residues. The ability of glue to bond depends 
upon the collective interaction of all of these fragments and the formation
cross-links and hydrogen bonds.

Each amino acid has a characteristic pH. This is a consequence of both the
acid and basic portions of the polypeptide. It will decide the buffering
capacity of the amino acid residues.

On a very practical level, a glue with a high acidity will set more slowly
and not be very water soluble. A glue that is basic will foam and have a
short shelf-life (basic conditions dissolve proteins). Neutral glues are
the best as they combine quick drying properties with a good life time. 
Remember that glue is protein and protein is food for molds and mildew. But
the over-riding condition for different manufacturers is their source 
material - which ultimately determines pH.

For more information, check out: 
http://sul-server-2.stanford.edu/don/dt/dt1560.html 


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