| MadSci Network: Chemistry |
Dear Michele;
For the iron to rust "Oxidize" there must be both water and oxygen present.
In pure water with no air present, iron reacts with water only very slowly.
In dry air, it also rusts very slowly. In the California desert, I have
seen tin cans still shiny after several years exposure.
The presence of salt in the water would speed up the reactions of air and
water with the iron since the salt water will conduct electricity much
better than plain tap water. Since the oxidation of iron [in fact,nearly
all corrosion] is an electrochemical reaction this would aid in the passage
of electrons. But, where the iron is covered with water, the access to air
is minimized, so rusting is slow.
You may have observed that the rusting appeared mostly at or just below the
water level.
Repeat this test with the steel wool only partly submerged in the salt
water, it may rust faster.
I am forwarding to you directly via eMail a response I made to a similar
query a few weeks ago. I hope it will answer some of your questions.
Charlie Crutchfield
Try the links in the MadSci Library for more information on Chemistry.