MadSci Network: Other |
Hi, Excellent question! I need to first assume you are asking about water- based glues like Elmer's glue. So based on this assumption I can answer the question. Water based glues (or even solvent based glues) work because the water (or solvent) evaporates (for example, the thinner you spread the glue, the faster it will dry as you increase the surface area, hence speeding up the amount of water evaporating). Since the water can not evaporate from a closed bottle, the glue remains "workable" so it can not stick to the sides. If you leave the cap off a bottle of glue and all the water would evaporate (this would take a long time), the glue would harden, but would still not stick to the bottle. The inside of the bottle is very smooth and the glue needs some roughness to grab causing the glue to stick. This is why Elmer's glue works well on paper as paper on the microscopic level is actually porous and the glue can grab it. Other glues that have a different solvent (that is not water, for instance an organic solvent) present may work better on some materials because the solvent present actually dissolves the piece you are interested in gluing. So there are actually 2 factors preventing the glue from sticking: (1) lack of water evaporation (the more important reason) and (2) smooth surface. As an experiment (if you'd like) put some Elmer's glue between two pieces of plastic wrap (like what you have in the kitchen, which is very similar to what a glue bottle is). First off you will notice it will take longer to dry than if you had glued two pieces of paper together. Second you will find that the two pieces of plastic will not be glued together. The dried glue should peel (rub it with your finger) leaving you with 3 pieces (2 pieces of plastic and 1 piece of dried glue, which is polyvinyl acetate). This worked for me when I tried it! If it didn't work, you must have some rough plastic wrap!! Now here's another question for you (and the answer is actually above hint see #2), how do non-stick surfaces (like Teflon) stick to the inside of a frying pan? Hope this helps, if not send in some more questions for clarification. KIP
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