MadSci Network: Chemistry |
Dear Baz, By searching the MadSci Archives using the keywords "color" + "light" , you will find information about the relationship between wavelengths of electromagnetic radiation on one hand and color, as perceived by the human eye, on the other hand. A colorimeter determines the relative percentages of light absorbed at different wavelengths - just like a spectrophotometer. Older (or simpler) instruments use filters to divide up the visible wavelength range, more sophisticated ones work with gratings. In every case, photocells measure the intensity of light transmitted (viz. reflected) by the sample at a number of wavelength bands. The intensity is related to the amount of a given colorant in (or on) the sample. The higher the colorant concentration, the lower the transmitted intensity (The first colorimeters were actually built to analyse concentrations of dissolved dyes). The data set obtained, together with the description of the type of light used (e.g. daylight or light bulb), is then used to compute "objective" measures of color. Various formulae are in use for this, e.g. CIE Lab values. A color is thus described by three coordinates. A bright yellow for instance has L=90, a=0, b=100. Color differences are computed using these coordinates by taking the "distance" like in ordinary Euclidean space (x,y,z). A distance ("delta E") of 2 units is usually just perceptible by the human eye. Where it starts to turn tricky is when you try to compare colors of sparkling lacquer with that of velvety tissue. Best Regards Werner Sieber
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