MadSci Network: Chemistry |
I am an IB Chem teacher and can't seem to find a logical answer to this question. Equilibrium constant expressions do not include solids because their concentration doesn't change. However, increasing the surface area of a solid reactant increases the rate of the forward reaction (more collisions). For a system at equilibrium that involves a solid reactant, why does the equilibrium position not shift to the right if more solid reactant is added, since effectively the surface area of the solid reactant is increased? Collision Theory and Le Chatelier suggest that it should, but it can't since it is not involved in the expression for K.
Re: Why doesn't increasing the surface area of a solid shift equilib position?
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