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C4H4O62- (aq) + 5 H2O2 (aq) ===> 4 CO2 (g) + 2 OH- (aq) + 6 H2O (l) According to one source I found, the above equation represents the reaction between the tartrate dianion (C4H4...)with hydrogen peroxide. The gas formed is then CO2. The reaction is catalyzed by the Cu+2 ion, so that is why nothing much happens until the copper sulfate solution is added. Notice that the OH- ion is also formed. That will tend to make the solution basic as the reation proceeds. It is also well known that a solution of tartrate dianion with Cu+2 ion will react slowly when base is added. In this reaction the Cu+2 oxidizes the tartrate, presumeably to CO2 and in the process the Cu+2 is reduced to Cu+1 ion which reacts with water (or oxygen) to produce Cu2O which is the red/orange precipitate. This reaction is accelerated by the heat from the other reaction. The green solution could be from a small amount of Cu+1 ion that remains in solution. It is also possible that the Cu+2 ion catalyzes the decomposition of some of the H2O2 to produce some oxygen as part of the gas. I like the general tone of the experiment as an illustration of the law od the conservation of mass. I wanted to get this off as an answer in a hurry. If you have more questions or I can be of more help contact me at jtfranzen@fuse.net Dr. Jerry Franzen
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