| MadSci Network: Chemistry | 
Oh boy, pickle engineering analysis!
This effect is most probably caused by the different wattage intercepted 
by the nail which is suspended from the pickle and is arcing through 
space, versus the nail which is contacting the salty pickle directly.  If 
the electric arc presents a large electrical resistance, while the direct 
contact between the nail and the pickel presents a small resistance, then 
a "flip-flop" situation exists, and the system is most stable when only 
one nail is arcing.  If true, then AC or DC makes no difference, and the 
effect is caused by the instability of two electric arcs connected in 
series.
Let's try assigning some crude numbers to this.  Suppose the pickel runs 
at about 50 watts, and suppose the electric arc has 100x more resistance 
than the direct metal/pickel contact.  Knowing that W=V^2/R, we can 
calculate that 120 volts at 50W gives a total resistance of nearly 300 
ohms, and if the resistance ratio is 100:1, then the electric arc has 
about 300 ohms while the direct metal/pickel contact has about 3 ohms.
What happens when we first plug the pickel into the wall?  Well, if both 
nails make contact with the pickle tissue at 3 ohms resistance, then the 
total power is V^2/R, (120*120)/(3+3) or 2400 watts!  Each nail would 
experience half the total, or 1200 watts.  With such a high wattage 
concentrated at the surface of the nails, the water in contact with the 
nails would fairly explode!  At this point a "random decision" would be 
made, because one nail would generate gas a bit faster than the other, and 
an electric arc would develop at one nail first.  The resistance of the 
arcing nail would rise to the 300 ohms we calculated before, and the total 
wattage being used by the pickle would fall drastically.  The total 
resistance of both nails in series goes from the 6 ohms of direct contact 
to the 303 ohms of one electric arc in series with one direct contact.  
The total energy goes back down to around 50W again, with almost all of it 
dissipated by the single electric arc, and the non-arcing nail loses the 
race.  The direct contact gets about 0.5 watt, while the electric arc gets 
the remaining 49.5 watts, and as a result, the nail with the direct 
contact stays cool and does not trigger an arc, while the electric arc 
self-heats, maintaining its own existance.  Once the arc appears at one 
end of the pickel, it tends to stay there.
Note that I'm picking these numbers out of the air, and making informed 
guesses as to what's occurring.  I think the general idea is correct, but 
the actual values might be quite different than I've speculated above.
Why would the arc move from one end to the other?  Well, have you
noticed that the electric arc tends to carve a large hollow inside the 
pickel?  In industrial settings this is called "electric discharge 
machining" and is used to carve odd-shaped holes in metal parts.  The arc 
is extremely hot, and it vaporizes any pickle tissue that it touches.  For 
this reason the arc tends to attack any bit of pickle tissue that 
protrudes, and when that part of the pickle is destroyed by the arc, the 
arc wanders to the next highest section of pickle-stuff.  After a moment 
the nail would have no supports, and would fall down and touch the pickle 
directly.  At this point the wattage would rise enormously again (because 
the two 3-ohm direct contacts in series present only 6 ohms load to the 
power supply).  Again the 2400 watts would blast the pickle, the "random 
decision" would occur, and one of the nails would heat its way into an 
electric arc state.  
As time went on, the nails would chew down through the pickel, randomly 
taking turns at supporting an electric arc, or at making direct contact 
with the pickle tissue.  And while the arc was staying at one end, it 
would continuously move along the nail, creating a strange 
flickering/crawling light pattern.
I've always been meaning to make an "artificial pickle" that was transparent inside. Cast a block of unflavored Jello with lots of salt added, then use it as a "pickle." The clear surface would give us a window on the mysteries taking place inside. This might make a good student project, eh?
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