MadSci Network: Chemistry |
Yes, the normal state of affairs is for water to contract when it is cooled at constant pressure; it is just the small region of the liquid below 4 degrees C that is the exception. The reason for the exception is that ice has an "open" structure that is less dense than liquid water. As you get close to the freezing point, the water starts to get a little icelike so it expands slightly. Then it expands a lot when it freezes, but if you then cool the solid ice further it contracts like most solids. Here is a table of the volume (in cubic centimeters) occupied by 1 gram of water at atmospheric pressure at various temperatures: Temperature (deg C) Volume (cm3/g) 90 1.035937 70 1.022741 50 1.012110 40 1.007845 30 1.004370 20 1.001796 10 1.000298 5 1.000033 4 1.000025 2 1.000057 0 (liquid) 1.000157 0 (ice) 1.09089 -10 1.08914 -20 1.08748 -30 1.08588 As for your question about the temperature at the polar caps, I don't know except to say it is usually quite cold. I suggest you resubmit that under the Earth Sciences category, or possibly with a search on the Web you might find information on the U.S. research station at the South Pole. Allan Harvey, aharvey@boulder.nist.gov "Don't blame the government for what I say, or vice-versa."
Try the links in the MadSci Library for more information on Chemistry.