MadSci Network: Chemistry |
Thanks for the question. Without more details about the paper towel you used in the experiment (there are a number of additives that are added to paper towels to improve strength, softness, absorbance, etc.), I won’t be able to determine all of the reactions and remaining components but I can give you some general guidance about what is happening in the experiment. Paper is made from tree fiber but the base material is cellulose, which is a natural polymer produced by trees and other plants. Cotton is another example of a natural cellulose. Bleach, also known as sodium hypochlorite (NaOCl) reacts with cellulose at high pH. Cellulose is a polymer that is formed by combining thousands of glucose units together. The bleach reacts with the cellulose polymer where the glucose units are connected, which cuts the polymer chain at that point. As more and more NaOCl reacts with the cellulose, the cellulose chains get shorter and shorter until only glucose units would remain. The reaction is an oxidation reaction carried out through a free radical mechanism. The temperature dependence that you observed is common in chemical reactions because chemical reactions occur faster at higher temperatures.
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